华电技术 ›› 2015, Vol. 37 ›› Issue (5): 14-20.

• 研究与开发 • 上一篇    下一篇

锅炉给水加氧对奥氏体管汽侧氧化皮形成及剥落的影响

  

  1. 1. 西安热工研究院有限公司, 西安 710032; 2. 华能玉环电厂, 浙江 玉环 317600
  • 出版日期:2015-05-25 发布日期:2015-10-08

Influence of the oxygenated treatment of boiler feedwater on forming and shedding of oxide skin in steam side of austenitic pipe

  1. 1. Xian Thermal Power Research Institute Company Limited, Xi an 710032, China; 2. Huaneng Yuhuan Power Plant, Yuhuan 317600, China

  • Online:2015-05-25 Published:2015-10-08

摘要:

摘 要: 对某电厂末级过热器和再热器锅炉管在不同加氧方式下不同时间段的管样进行了管材显微组织分析、晶粒度测量、内壁氧化层金相分析、典型内壁氧化层结构的扫描式电子显微镜( SEM) 和 X 射线能谱仪( EDS) 分析。 结果表明: 给水加氧促进了管子内壁氧化层外层 Fe2O3 的形成;其中 1 台锅炉的末级再热器管样氧化程度最严重, 内壁无细晶带的管样比例偏高;内壁未能形成均匀连续的富 Cr 层是其较早发生氧化皮集中剥落的主要原因之一, 给水加氧是氧化层脱落.

关键词: 关键词: 锅炉, 加氧, 内壁氧化层, 富 Cr 层, 剥落

Abstract:

Abstract:The pipes of the finishing superheater and the reheater of the boiler of a power plant were investigated experimentally.The pipe samples were obtained in different time periods under different oxygenation treatment modes. The experimental methods includes the microstructure analysis,the grain size measurement, the inner wall oxide layer metallographic analysis and the scanning electron microscope ( SEM) analysisand Xray energy dispersive spectrometer ( EDS) analysis for typical inner wall oxide layer structure.The results show that the feedwater oxygenatin treatment can acilitate forming of Fe2O3 outer shell of oxyde layer in pipe inner wall.The sample tubes of the finalstage reheater of a boiler were oxygenated most seriously, the percentage of the sample tubes,in which there was not the fine grain zone in inner wall, is larger. In the inner wall of the sample tubes,the uniform and continous Crrich layer did not formed, and this is one of the main reasons caused the oxide skin to shed concentratedly.The feedwater oxygenation treatment is a factor to promote the oxyde skin to shed.