华电技术 ›› 2020, Vol. 42 ›› Issue (3): 52-58.

• 超低排放与碳减排 • 上一篇    下一篇

一种新型氨法脱硫超低排放技术的特点及应用

  

  1. 中国华电科工集团有限公司,北京 100070
  • 出版日期:2020-03-25

Technical characteristics and application of a new ammonia desulfurization ultra-low emission technology #br#

  1. China Huadian Engineering Company Limited,Beijing 100070,China
  • Published:2020-03-25

摘要: 为了解决氨法脱硫工艺常见的可溶性盐、气溶胶等粉尘排放超标问题,某公司研发了一种新型氨法脱硫超
低排放技术。该技术基于塔内结晶、塔外氧化的技术理念,对吸收塔浓缩区、吸收区、水洗区和除尘除雾区分别进
行了针对性设计,采用2级不同质量浓度梯度的水洗层并将高效除尘除雾器与 2级雾沫精除器进行组合;塔外氧化
槽采用3层分布板技术,达到了充分氧化的目的,整体氧化率大于99%;2级水洗槽分质量浓度控制、逐级补水技术
也最大限度地提高了水洗效果,保证了系统的水平衡。该技术应用于华电能源股份有限公司富拉尔基热电厂氨法
脱硫超低排放改造项目中,能满足国家超低排放要求,并通过了运行检验。

关键词: 氨法脱硫, 超低排放, 塔内结晶, 塔外氧化, 不同质量浓度水洗层, 高效除尘除雾器, 雾沫精除器

Abstract: In order to solve the excessive discharges of soluble salts,aerosols and other dusts that are common in the
ammonia desulfurization process,a new ammonia desulfurization ultra-low emission technology was developed. Adopting
the concept of crystallization in the tower and oxidation outside the tower,the technology takes specific designs on the
concentration area,absorption area,water scrubbing area and dust/mist removal area of the absorption tower respectively.
Two-stage water scrubbers with different mass concentrations, are combined with high-efficiency demisters and
precipitators,and two-stage mist eliminators. The oxidation tank outside the tower adopting three-layer distribution plate
technology can fully oxidize the slurry,and its overall oxidation rate is over 99%. Two-stage water scrubbing tank can
maximize the washing effect by controlling the mass concentration and taking stage-by-stage water replenishment,which
ensures the water balance of the system. This technology is applied in the ammonia desulfurization ultra-low emission
reconstruction in Fulaerji Thermal Power Plant of Huadian Environmental Protection Engineering & Technology Company
Limited.It can meet the requirements of the national ultra-low emission standards and pass the operation test.

Key words: ammonia desulfurization, ultra-low emission, crystallization in the tower, oxidation outside the tower, water
scrubbing layers of different mass concentrations,
high-efficiency demister and precipitator, mist eliminator