华电技术 ›› 2020, Vol. 42 ›› Issue (10): 95-98.

• 燃烧与混燃 • 上一篇    

半焦和烟煤混合燃料挥发分释放和氮转化特性

  

  1. 哈尔滨锅炉厂有限责任公司 高效清洁燃煤电站锅炉国家重点实验室,哈尔滨 150046
  • 出版日期:2020-10-25

Devolatilization and nitrogen conversion characteristics of the mixture of semi-coke and bituminous coal

  1. State Key Laboratory of Efficient and Clean Coal-fired Utility Boilers,Harbin Boiler Company Limited,Harbin 150046,China
  • Published:2020-10-25

摘要: 为实现半焦在煤粉锅炉中的大比例掺烧、降低 NOx 的排放,以管式沉降炉为例,研究了烟煤和半焦不同比
例混合后的挥发分释放特性和氮转化特性。研究结果表明,在温度一定的条件下,混合燃料挥发分的释放率与半
焦的掺混比例、在炉内的停留时间相关:挥发分的释放率随半焦掺混比例的提高而降低,随停留时间的增加而提
高,最大挥发分释放率大于其工业分析值;同时,随着半焦掺混比例的增加,混合燃料的焦炭氮呈上升趋势,挥发分
氮呈减少趋势;当掺混的半焦超过混合煤粉质量的 50% 时,焦炭氮占比较其在原煤中的占比增加了 6.08%,NOx 排放
的控制难度会增大。

关键词: 半焦, 烟煤, 掺混, 挥发分释放, 挥发分氮, 焦炭氮, NOx 排放

Abstract: In order to apply semi-coke to large-proportion co-combustion in pulverized coal boilers and reduce NOx
emission,the study on devolatilization and nitrogen conversion characteristics of bituminous coal and semi-coke blends
under different mixing proportions are made on a dropping tube furnace. The results show that under certain temperature,
the release rate of volatile matters is related to the mixing proportion and the residence time in the furnace. The release rate
of volatile matters decreases as the mixing proportion of semi-coke increases,and accumulates with the increase of the
residence time. The maximum release rate of volatile matters is greater than that in proximate analysis. And with the
increase of the blending proportion of semi-coke,the char nitrogen from the blend shows an upward trend,and the volatile
nitrogen shows a downward trend. When the proportion of semi-coke exceeds 50% of the blend,the char nitrogen of the
blend increases by 6.08% compared with that of the raw coal,thus the difficulty of NOx emission control increases.

Key words: semi-coke, bituminous coke, blending, devolatilization, volatile nitrogen, char nitrogen, NOx emission