With the increasingly growing demand on energy and prominent environmental crisis,catalytic pyrolysis of pretreated biomass has become a decent technical rout for the preparation of liquid fuels, a sustainable resource. However, the bio-oil generated from the direct pyrolysis of biomass has a complex composition, low calorific value, high oxygen content and strong acidity, which restricts its application. Thus, the main factors affecting the quality of bio-oil are analyzed from the pyrolysis mechanism, biomass pretreatment, catalyst selection and the coupling of pretreatment and catalytic pyrolysis. Pretreatment process will prolong the preparation time, and catalyst will lower the production of bio-oil. The coupling technology is a promising solution to the difficulties mentioned. To prepare high-quality liquid fuels by biomass pyrolysis rapidly, the following researches should target on how to make directional preparation on hydrocarbon-rich bio-oil by biomass pyrolysis, select and optimize the catalysts, and couple the pretreatment process with catalytic pyrolysis.