华电技术 ›› 2016, Vol. 38 ›› Issue (12): 45-49.

• 节能与环保 • 上一篇    下一篇

环境因素对纯钛在脱硫湿烟气冷凝液中腐蚀行为的影响

  

  1. 1.华电郑州机械设计研究院有限公司,郑州〓450015; 2.中国科学院金属研究所,沈阳〓110016
  • 出版日期:2016-12-25 发布日期:2017-02-04

Effect of environment factor to corrosion behavior on pure titanium in desulfurized wet flue gas condensate

  1. 1.Huadian Zhengzhou Mechanical Design Institute Company Limited, Zhengzhou 450015, China; 2.Institute of Metal Research, Chinese Academy of Science, Shenyang 110016, China
  • Online:2016-12-25 Published:2017-02-04

摘要:

摘要:工业纯钛以其优良的耐蚀性能被认为是作为火电厂脱硫湿烟囱防腐内衬的理想材料,采用腐蚀电化学的方法系统研究了环境因素对TA2纯钛在模拟脱硫湿烟气冷凝液中耐蚀性能的影响。研究结果表明,纯钛的耐蚀性能主要取决于冷凝液的pH值和HF含量,当pH值大于3.0或者HF含量足够低时,纯钛表现为自钝化行为,具有较高的耐蚀性,反之其表现为活化-钝化行为,耐蚀性较差。另外,温度和流速均能加速纯钛在模拟冷凝液中的腐蚀速率,其机制都是加速了HF所引起的阳极钝化膜的溶解过程。

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Abstract:

Abstract:Due to fine corrosion resisting property, industrial pure titanium is considered as the ideal material for thermal power plant desulfurization wet stack anticorrosion liner. Adapted corrosion electrochemistry method, the effect of environment factor to corrosion resisting property on TA2 pure titanium in simulated desulfurized wet flue gas condensate was studied. The result indicated that the corrosion resisting property of pure titanium was mainly determined by pH and HF content of the condensate. If pH is higher than 3.0 or HF content is low enough, pure titanium is in selfpassivation behavior, with high corrosion resisting property. In contrast, pure titanium is in activationpassivation behavior, corrosion resisting property is relatively poor. In addition, temperature and flow velocity of condensate increased corrosion rate. Other changes were caused by anodic passive film dissolution due to HF was accelerated. 

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