酸洗和磷酸浸渍对浮萍热解特性的影响研究

doi:10.3969/j.issn.2097-0706.2023.05.005

综合智慧能源 ›› 2023, Vol. 45 ›› Issue (5): 39-45.doi: 10.3969/j.issn.2097-0706.2023.05.005

酸洗和磷酸浸渍对浮萍热解特性的影响研究

杨伟¹(), 吕雷达¹, 彭诗阳²^,³, 李威²^,³, 蔡红春²^,³, 韩勇¹, 朱有健¹^,^*(), 杨海平⁴, 赵海⁵

1.郑州轻工业大学能源与动力工程学院，郑州 450002
2.禹州市鑫恒环境科技有限公司，河南禹州 452570
3.禹州市鑫恒现代农业创新研究院有限公司，河南禹州 452570
4.华中科技大学煤燃烧国家重点实验室，武汉430074
5.中国科学院成都生物研究所，成都 610041

收稿日期:2022-10-31 修回日期:2022-12-25 出版日期:2023-05-25 发布日期:2023-05-27
通讯作者: *朱有健（1987），男，副教授，博士，从事生物质资源高值化利用等方面的研究， yjzhu01@hotmail.com。
作者简介:杨伟（1988），男，讲师，博士，从事可再生能源清洁利用等方面的研究， weiyang_4105@yeah.net；
基金资助:
郑州轻工业大学博士科研基金项目(2019BSJJ010);国家自然科学基金项目(51706210);河南省高等学校重点科研项目(23A470008)

Effect of acid pickling and phosphoric acid impregnation on pyrolysis characteristics of duckweed

YANG Wei¹(), LYU Leida¹, PENG Shiyang²^,³, LI Wei²^,³, CAI Hongchun²^,³, HAN Yong¹, ZHU Youjian¹^,^*(), YANG Haiping⁴, ZHAO Hai⁵

1. School of Energy and Power Engineering， Zhengzhou University of Light Industry，Zhengzhou 450002， China
2. Yuzhou Xinheng Environmental Technology Company Limited， Yuzhou 452570， China
3. Yuzhou Xinheng Modern Agriculture Innovation Research Institute Company Limited， Yuzhou 452570， China
4. State Key Laboratory of Coal Combustion， Huazhong University of Science and Technology，Wuhan 430074， China
5. Chengdu Institute of Biology， Chinese Academy of Sciences， Chengdu 610041， China

Received:2022-10-31 Revised:2022-12-25 Online:2023-05-25 Published:2023-05-27
Supported by:
Doctoral Scientific Research Foundation of Zhengzhou University of Light Industry(2019BSJJ010);National Natural Science Foundation of China(51706210);Key Scientific Research Projects of Colleges and Universities in Henan Province(23A470008)

摘要/Abstract

摘要：

基于当前浮萍热解研究不足的现状，探究浮萍热解特性及磷对热解气体产物特性的影响。采用酸洗及磷酸浸渍的方法对浮萍进行处理，使用热重红外联用仪探究酸洗和磷酸浸渍对浮萍热解特性及气体产物特性的影响。研究发现酸洗明显降低了浮萍的灰分含量且改变了灰分组分，提高了样品的热值及C，H，N，O的质量分数。热重试验发现浮萍热解主要分为4个阶段，热解反应主要发生在145~520 ℃，微商热重（DTG）曲线呈双峰分布。酸洗导致热解初温升高10 ℃，降低了浮萍热解后的固体产物产量，降低了最大失重峰温度，但最大失重速率上升。磷酸浸渍明显提高了浮萍热解后的固体产物产量，同时降低了热解的最大失重峰温度及最大失重速率。酸洗使热解气体产物CH₄含量升高，而磷酸浸渍则促使CH₄，CO₂，NH₃等气体产量显著增加且明显扩大了NH₃的释放区间。

关键词: 浮萍, 酸洗, 磷酸, 浸渍, 热解, 热重, CH₄, CO₂, NH₃

Abstract:

Based on the deficiencies of the researches on duckweed pyrolysis， the effects of duckweed pyrolysis and phosphorus on the characteristics of pyrolysis gas products were explored. Pickling and phosphoric acid impregnation were used to treat duckweed，and their treatment effects on the pyrolysis characteristics and gas product characteristics of duckweed were investigated by TG-FTIR. It was found that pickling significantly reduced the ash content of duckweed and changed its ash components. In addition， pickling increased the contents of C， H， N and O， and increased the calorific value of the samples. Thermogravimetric results showed that duckweed pyrolysis was mainly divided into four stages. Pyrolysis reaction mainly occurred between 145 and 520 ℃， and the pyrolysis DTG curve showed bimodal distribution. Pickling resulted in a 10 ℃ initial temperature rise， drops of solid product yield after duckweed pyrolysis and the maximum weight loss temperature， and an increase of the maximum weight loss rate. Phosphoric acid impregnation significantly increased the yield of solid products of duckweed pyrolysis， and decreased the maximum weight loss temperature and the maximum weight loss rate. Pickling increased the content of CH₄， while phosphoric acid impregnation significantly facilitated the production of CH₄， CO₂ and NH₃， and greatly widened the release range of NH₃.

Key words: duckweed, acid pickling, phosphoric acid, impregnation, pyrolysis, thermogravimetry, CH₄, CO₂, NH₃

中图分类号:

杨伟, 吕雷达, 彭诗阳, 李威, 蔡红春, 韩勇, 朱有健, 杨海平, 赵海. 酸洗和磷酸浸渍对浮萍热解特性的影响研究[J]. 综合智慧能源, 2023, 45(5): 39-45.

YANG Wei, LYU Leida, PENG Shiyang, LI Wei, CAI Hongchun, HAN Yong, ZHU Youjian, YANG Haiping, ZHAO Hai. Effect of acid pickling and phosphoric acid impregnation on pyrolysis characteristics of duckweed[J]. Integrated Intelligent Energy, 2023, 45(5): 39-45.

图/表 7

表1

表2

图1

图2

表3

图3

图4

参考文献 33

[1]	WANG K, BROWN R C. Catalytic pyrolysis of microalgae for production of aromatics and ammonia[J]. Green Chemistry, 2013, 15(3): 675-681. doi: 10.1039/c3gc00031a
[2]	MADDI B, VIAMAJALA S, VARANASI S. Comparative study of pyrolysis of algal biomass from natural lake blooms with lignocellulosic biomass[J]. Bioresource Technology, 2011, 102(23): 11018-11026. doi: 10.1016/j.biortech.2011.09.055 pmid: 21983407
[3]	SOTOUDEHNIAKARANI F, ALAYAT A, MCDONALD A G. Characterization and comparison of pyrolysis products from fast pyrolysis of commercial Chlorella vulgaris and cultivated microalgae[J]. Journal of Analytical and Applied Pyrolysis, 2019, 139: 258-273. doi: 10.1016/j.jaap.2019.02.014
[4]	NGUYEN T B, TRUONG Q M, CHEN C W, et al. Pyrolysis of marine algae for biochar production for adsorption of ciprofloxacin from aqueous solutions[J]. Bioresource Technology, 2022, 351: 127043. doi: 10.1016/j.biortech.2022.127043
[5]	CAMPANELLA A, HAROLD M P. Fast pyrolysis of microalgae in a falling solids reactor: Effects of process variables and zeolite catalysts[J]. Biomass & Bioenergy, 2012, 46: 218-232.
[6]	FUENTES M, NOWAKOWSKI D, KUBACKI M, et al. Survey of influence of biomass mineral matter in thermochemical conversion of short rotation willow coppice[J]. Journal of the Energy Institute, 2008, 81(4):234-241. doi: 10.1179/014426008X370942
[7]	CHEN X, WU H. Effect of phosphorus (P) on the structure and reactivity of biochars produced from the pyrolysis of acid-washed biomass loaded with P of various forms[J]. Proceedings of the Combustion Institute, 2021, 38(3): 3959-3967. doi: 10.1016/j.proci.2020.06.287
[8]	BLASI C D. Kinetic and heat transfer control in the slow and flash pyrolysis of solids[J]. Industrial & Engineering Chemistry Research, 1996, 35(1): 37-46. doi: 10.1021/ie950243d
[9]	KANG X, ZHU H, WANG C, et al. Biomass derived hierarchically porous and heteroatom-doped carbons for supercapacitors[J]. Journal of Colloid and Interface Science, 2018, 509: 369-383. doi: S0021-9797(17)31031-7 pmid: 28923734
[10]	KUMAR A, JONES D D, HANNA M A. Thermochemical biomass gasification: A review of the current status of the technology[J]. Energies, 2009, 2(3): 556-581. doi: 10.3390/en20300556
[11]	陈旭. 生物质富钙热解过程中生物油脱氧机理及调控机制研究[D]. 武汉: 华中科技大学, 2018.
	CHEN Xu. Study on the mechanism and regulatory mechanism of bio-oil deoxygenation during calcium-rich pyrolysis of biomass[D]. Wuhan: Huazhong University of Science and Technology, 2018.
[12]	YANG W, ZHU Y, CHENG W, et al. Characteristics of particulate matter emitted from agricultural biomass combustion[J]. Energy & Fuels, 2017, 31(7):7493-7501. doi: 10.1021/acs.energyfuels.7b00229
[13]	齐鹏刚, 苏银海, 张书平, 等. 酸洗预处理对生物质热解焦物理化学特性的影响[J]. 太阳能学报, 2022, 43(8): 441-446. doi: 10.19912/j.0254-0096.tynxb.2021-0024
	QI Penggang, SU Yinhai, ZHANG Shuping, et al. Effect of pickling pretreatment on physicochemical properties of biomass pyrolytic coke[J]. Journal of Solar Energy, 2022, 43(8): 441-446.
[14]	KNUDSEN J N, JENSEN P A, DAM-JOHANSEN K. Transformation and release to the gas phase of Cl, K, and S during combustion of annual biomass[J]. Energy & Fuels, 2004, 18(5): 1385-1399. doi: 10.1021/ef049944q
[15]	NOACK S R, MCLAUGHLIN M J, SMERNIK R J, et al. Crop residue phosphorus: Speciation and potential bio-availability[J]. Plant and Soil, 2012, 359(1): 375-385. doi: 10.1007/s11104-012-1216-5
[16]	MURADOV N, FIDALGO B, GUJAR A C, et al. Pyrolysis of fast-growing aquatic biomass—Lemna minor (duckweed): Characterization of pyrolysis products[J]. Bioresource Technology, 2010, 101(21): 8424-8428. doi: 10.1016/j.biortech.2010.05.089
[17]	牛琦. 典型藻类生物质热解实验与机理研究[D]. 天津: 天津大学, 2018.
	NIU Qi. Experimental and mechanistic study of pyrolysis of typical algal biomass[D]. Tianjin: Tianjin University, 2018.
[18]	LI F, SRIVATSA S C, BATCHELOR W, et al. A study on growth and pyrolysis characteristics of microalgae using thermogravimetric analysis-infrared spectroscopy and synchrotron fourier transform infrared spectroscopy[J]. Bioresource Technology, 2017, 229: 1-10. doi: S0960-8524(17)30018-4 pmid: 28088575
[19]	GAO W, CHEN K, XIANG Z, et al. Kinetic study on pyrolysis of tobacco residues from the cigarette industry[J]. Industrial Crops and Products, 2013, 44: 152-157. doi: 10.1016/j.indcrop.2012.10.032
[20]	LI Y, XIN Y, WANG X, et al. Fixed bed reactor pyrolysis of rape straw: Effect of dilute acid pickling on the production of bio-oil and enhancement of sugars[J]. Industrial & Engineering Chemistry Research, 2020, 59(39): 17564-17574. doi: 10.1021/acs.iecr.0c02011
[21]	黄顺进, 张坤, 张润衡, 等. 沙棘树枝热解产物分布及产物表征[J]. 广东化工, 2021(4):33-35.
	HUANG Shunjin, ZHANG Kun, ZHANG Runheng, et al. Distribution and characterization of pyrolysis products from seabuckthorn branches[J]. Guangdong Chemical Industry, 2021(4):33-35.
[22]	WANG Q, HAN K, GAO J, et al. Investigation of maize straw char briquette ash fusion characteristics and the influence of phosphorus additives[J]. Energy & Fuels, 2017, 31(3): 2822-2830. doi: 10.1021/acs.energyfuels.7b00047
[23]	LIU W J, LI W W, JIANG H, et al. Fates of chemical elements in biomass during its pyrolysis[J]. Chemical Reviews, 2017, 117(9): 6367-6398. doi: 10.1021/acs.chemrev.6b00647
[24]	马中青, 张齐生. 温度对马尾松热解产物产率和特性的影响[J]. 浙江农林大学学报, 2016, 33(1): 109-115.
	MA Zhongqing, ZHANG Qisheng. Effect of temperature on yield and characteristics of pyrolysis products of masson pine[J]. Journal of Zhejiang A&F University, 2016, 33(1):109-115.
[25]	高现文, 单春贤, 李海英, 等. 温度对污泥热解产物及特性的影响[J]. 生态环境, 2007, 16(4): 1189-1192.
	GAO Xianwen, SHAN Chunxian, LI Haiying, et al. Effect of temperature on pyrolysis products and characteristics of sludge[J]. Ecology and Environment, 2007, 16(4):1189-1192.
[26]	车长波, 袁际华. 世界生物质能源发展现状及方向[J]. 天然气工业, 2011, 31(1):104-106.
	CHE Changbo, YUAN Jihua. Development status and direction of biomass energy in the world[J]. Natural Gas Industry, 2011, 31(1):104-106.
[27]	胡亿明. 木质生物质各组分热解过程和热力学特性研究[D]. 北京: 中国林业科学研究院, 2014.
	HU Yiming. Study of pyrolysis processes and thermodynamic properties of various components of woody biomass[D]. Beijing: Chinese Academy of Forestry, 2014.
[28]	MIAO X, WU Q, YANG C. Fast pyrolysis of microalgae to produce renewable fuels[J]. Journal of Analytical and Applied Pyrolysis, 2004, 71(2): 855-863. doi: 10.1016/j.jaap.2003.11.004
[29]	顾新娇, 王文国, 胡启春. 浮萍环境修复与生物质资源化利用研究进展[J]. 中国沼气, 2013, 31(5): 15-19.
	GU Xinjiao, WANG Wenguo, HU Qichun. Research progress on environmental remediation and biomass utilization of duckweed[J]. China Biogas, 2013, 31(5):15-19.
[30]	CAMPANELLA A, HAROLD M P. Fast pyrolysis of microalgae in a falling solids reactor: Effects of process variables and zeolite catalysts[J]. Biomass and Bioenergy, 2012, 46: 218-232. doi: 10.1016/j.biombioe.2012.08.023
[31]	任衍森, 马腾, 周毅, 等. 温度对棉花秸秆热解固液相产物特性的影响[J]. 石河子大学学报(自然科学版), 2020, 38(6): 668-674.
	REN Yansen, MA Teng, ZHOU Yi, et al. Effect of temperature on characteristics of solid and liquid products during pyrolysis of cotton straw[J]. Journal of Shihezi University(Natural Science Edition), 2020, 38(6):668-674.
[32]	王莹. 酸洗-烘焙联合预处理对谷子秸秆及谷糠热解特性影响研究[D]. 沈阳: 沈阳农业大学, 2020.
	WANG Ying. Study on the effect of combined pickling-baking pretreatment on the pyrolysis characteristics of cereal straw and bran[D]. Shenyang: Shenyang Agricultural University, 2020.
[33]	LIU G, WRIGHT M M, ZHAO Q, et al. Catalytic fast pyrolysis of duckweed: Effects of pyrolysis parameters and optimization of aromatic production[J]. Journal of Analytical and Applied Pyrolysis, 2015, 112: 29-36. doi: 10.1016/j.jaap.2015.02.026

项目		DW	ADW
工业分析/%	w(A)	21.38	6.98
	w(V)	69.91	72.64
	w(FC)	8.71	20.38
元素分析/%	w(C)	36.36	44.70
	w(H)	5.38	6.39
	w(N)	5.34	6.63
	w(S)	0.48	0.37
	w(O)	31.06	34.93
Q_HHV/(MJ·kg^-1)		15.41	19.40
主要成分质量分数/%	纤维素	14.26
	蛋白质	21.50
	淀粉	47.80
	木质素	1.16

样品	灰分质量分数
样品	K₂O	CaO	Na₂O	MgO	Al₂O₃	SiO₂	P₂O₅	Fe₂O₃
DW	17.71	33.72	2.74	6.08	2.06	17.27	16.91	3.51
ADW	0.66	0.53	3.33	0.81	2.15	78.13	12.81	1.59

样品	热解初温/℃	t_max/℃	v_DTG,max/ (%·min^-1)	热解终温/℃	失重率/%
DW	145	320	-4.16	520	37.08
ADW	155	300	-4.32	510	30.43
ADW-5P	150	275	-3.31	530	38.65
ADW-10P	145	255	-2.99	540	44.19
ADW-20P	145	230	-3.02	550	49.49

酸洗和磷酸浸渍对浮萍热解特性的影响研究

Effect of acid pickling and phosphoric acid impregnation on pyrolysis characteristics of duckweed

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 33

相关文章 15

编辑推荐

Metrics

本文评价

[1]	范德锴, 付洁, 刘洋, 周春宝, 代建军. 纤维素热解制备高值化学品的研究综述[J]. 综合智慧能源, 2023, 45(5): 24-31.
[2]	蒋雨辰, 李清扬, 胡勋. 基于微波热解技术制备生物炭的研究进展[J]. 综合智慧能源, 2023, 45(5): 46-62.
[3]	陈文轩, 李学琴, 刘鹏, 李艳玲, 卢岩, 雷廷宙. 催化生物质焦油模型化合物热解规律的研究[J]. 综合智慧能源, 2023, 45(5): 63-69.
[4]	房瑞, 段志勇, 刘在智, 王宇轩, 刘辰希, 李浩, 范垂钢. 海洋垃圾治理技术综述[J]. 综合智慧能源, 2023, 45(5): 70-79.
[5]	李敏霞, 侯焙然, 王派, 董丽玮, 田华. 二氧化碳跨临界循环热泵的应用与发展[J]. 综合智慧能源, 2023, 45(4): 12-18.
[6]	韩倩雯, 张琨, 陈晓阳, 朱腾龙. La/Ni共掺杂SrTi_0.35Fe_0.65O_3-_δ对称电极用于SOEC共电解H₂O/CO₂研究[J]. 综合智慧能源, 2022, 44(8): 43-47.
[7]	魏书洲, 李兵发, 孙晨阳, 周兴, 王亚龙, 邹一帆, 邓靖敏, 王金星. 压缩空气储能技术及其耦合发电机组研究进展[J]. 华电技术, 2021, 43(7): 9-16.
[8]	赵大周, 王明祥, 阮慧锋, 谷菁, 王明晓. 分布式能源站天然气内燃机Urea-SCR系统模拟优化研究[J]. 华电技术, 2021, 43(5): 45-52.
[9]	连少翰, 李润, 张泽洲, 刘庆岭, 韩瑞, 赵军, 宋春风. 复合膜在CO₂分离领域的研究进展[J]. 华电技术, 2021, 43(11): 128-137.
[10]	代宝民, 刘圣春, 曹钰, 杨海宁, 冯一宁, 肖鹏. 商超自然工质CO₂制冷系统增效技术及碳减排预测[J]. 华电技术, 2021, 43(11): 74-84.
[11]	戴若薇, 赵瑞东, 秦建光, 陈天举, 吴晋沪. 热解半焦与褐煤掺烧及气体污染物排放特性 TG-FTIR 研究[J]. 华电技术, 2020, 42(7): 28-34.
[12]	郑少伟，王志强*，王鹏，程星星，许焕焕. 热解半焦的清洁高效利用现状及研究进展[J]. 华电技术, 2020, 42(7): 42-49.
[13]	郑洪岩, 贾丁丁, 赵言, 冯智皓, 白宗庆. 气化残炭与低阶煤混燃特性及动力学分析[J]. 华电技术, 2020, 42(7): 74-80.
[14]	邵磊，潘广强，张裕全，储昊，曹伟. 声波解堵提效技术在尿素热解炉上的应用[J]. 华电技术, 2020, 42(6): 43-46.
[15]	冯力勇，张云. 考虑电池能效的电网侧电化学储能电站最优功率控制策略研究[J]. 华电技术, 2020, 42(4): 37-41.