Advances of composite membranes in CO2 separation

doi:10.3969/j.issn.1674-1951.2021.11.014

Abstract

Abstract:

In order to achieve carbon peak and carbon neutrality, it is necessary to develop CO₂ capture, storage and resource utilization （CCUS） technology to control CO₂ emissions. As one of the most common gas separation technologies, membrane-based separation has been widely used in the CO₂ capture of flue gas from power plants and the purification of natural gas. It has the advantages of low energy consumption, easy operation, small site area, easy expansion and low operating costs,compared to absorption, adsorption and cryogenic methods. However, pure inorganic membranes and polymer membranes can hardly be used in large-scale applications for their own shortcomings. The development of composite membranes with superior gas separation performance has become the hotspot.The research progress of composite membranes on CO₂ capture was reviewed. Being sorted by their structures,composite membranes include mixed-matrix membranes and supported liquid membranes. The separation performances of different composite membranes were compared. Based on their advantages and disadvantages,the key issues restricting the development of composite membranes were analyzed and discussed. Finally, the development direction of composite membrane-based gas separation technology was also prospected.

Key words: carbon neutrality, CCUS, membrane-based separation, mixed-matrix membrane, supported liquid membrane, ionic liquid, carbonic anhydrase

CLC Number:

X701.7

LIAN Shaohan, LI Run, ZHANG Zezhou, LIU Qingling, HAN Rui, ZHAO Jun, SONG Chunfeng. Advances of composite membranes in CO₂ separation[J]. Huadian Technology, 2021, 43(11): 128-137.

Figures/Tables 5

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References 76

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填料/聚合物基质	CO₂的渗透性/Barrer	CO₂/N₂ 选择性	参考文献
GO/HCM	474	56.0	[12]
ZIF-8/Pebax	100	60.0	[13]
ZIF-67/Pebax	162	81.0	[14]
MIL-101/Pebax	71	47.0	[15]
MIL-53/Pebax	129	58.0	[16]
OH-ZIF/Pebax	273	38.0	[17]
NH₂-MIL-101/Pebax	74	43.0	[15]
NH₂-MIL-53/CA	53	23.0	[18]
NH₂-MIL-53/Pebax	149	55.0	[16]
COF-5/Pebax	493	49.0	[19]
SNW-1/PIM-1	7 954	20.0	[20]

填料/聚合物基质	CO₂的渗透性/ Barrer	CO₂/N₂ 选择性	参考文献
Glycerol/Pebax	50	233.0	[46]
[BMIM][CF₃SO₃] /Pebax	300	40.0	[41]
[Bmim][BF₄]/Nexar	200	130.0	[40]
Poly([Pyr11][C(CN)3]/[C2mim][C(CN)3]	439	64.0	[38]
Poly([Pyr11][C(CN)3]/[C2mim][B(CN)4]	472	54.0	[39]
mPEG/Nafion	446	31.0	[45]

成分	CO₂的渗透性/Barrer	CO₂/N₂ 选择性	CO₂/CH₄ 选择性	参考文献
Pebax/ILs/NiZnFe₄O₄	300	248.0	—	[56]
Pebax/Glycerol/Cu	64	200.0	—	[46]
Matrimid/PEG 200/ZSM-5	11	—	60.0	[59]
Pebax/[Hmim][NTf]/LDHN	644	—	34.0	[55]
PES/[EMIM][NTf₂]/h-BN	747 252	—	1.8	[54]
PES/[EMIM][NTf₂]/MoS₂	153 112	—	1.4	[54]

成分	CO₂的渗透性/Barrer	CO₂/N₂ 选择性	参考文献
[Benz][Ac]/PI	19	40.0	[67]
[BMIM][AC]/PVDF	520	22.0	[66]
[EtDBN][B(CN)4]/PES	1 583	48.0	[64]
SspCA/[C4mim][Tf2N]/PVDF	734	36.0	[75]

成分	CO₂的渗透性/GPU	CO₂/N₂ 选择性	参考文献
Mico/[BMIM][BF₄]	80	87.0	[72]
GO/[BMIM][BF₄]	68	382.0	[71]
WS₂/[BMIM][BF₄]	47	153.0	[70]
MoS₂/[BMIM][BF₄]	47	131.0	[69]
uGO/[EMIM][Ac]	37	130.0	[74]

Advances of composite membranes in CO₂ separation

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