Preparation of biomass-based carbon materials and its application as electrodes in supercapacitors

doi:10.3969/j.issn.2097-0706.2023.05.001

Abstract

Abstract:

Biomass materials are considered as important carbon sources for the industrialized preparation of new carbon materials， due to the low price， convenience of collection， high aromaticity and carbon content. The efficient and sustainable conversion from biomass materials to functional materials is the key to achieving carbon neutrality. Porous carbon materials have great potential for energy storage due to their high specific surface area， abundant and reasonable porous structure， good electrical conductivity and stability. The latest researches at home and abroad on the classification and preparation of the porous carbon materials derived from biomass are summarized， focusing on its application as the electrode material. And the future research direction is providing reasonable preparation processes for biomass-based porous carbon materials according to the advantages and characteristics of various biomass.

Key words: carbon neutrality, biomass, porous carbon material, preparation method, supercapacitor, electrode, energy storage

CLC Number:

TK6：TM53

ZHOU Shuxin, FAN Huailin, HU Xun. Preparation of biomass-based carbon materials and its application as electrodes in supercapacitors[J]. Integrated Intelligent Energy, 2023, 45(5): 1-12.

Figures/Tables 7

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Table 1

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References 107

[1]	ABNISA F, DAUD W M A W. A review on co-pyrolysis of biomass:An optional technique to obtain a high-grade pyrolysis oil[J]. Energy Conversion and Management, 2014, 87: 71-85. doi: 10.1016/j.enconman.2014.07.007
[2]	WANG Z, SHEN D, WU C, et al. State-of-the-art on the production and application of carbon nanomaterials from biomass[J]. Green Chemistry, 2018, 20: 5031-5057. doi: 10.1039/C8GC01748D
[3]	WANG Z, SMITH A T, WANG W, et al. Versatile nanostructures from rice husk biomass for energy applications[J]. Angewandte Chemie, 2018, 57: 13722-13734.
[4]	PRADHAN P, MAHAJANI S M, ARORA A. Production and utilization of fuel pellets from biomass: A review[J]. Fuel Processing Technology, 2018, 181: 215-232. doi: 10.1016/j.fuproc.2018.09.021
[5]	LIU C, WANG H, KARIM A M, et al. Catalytic fast pyrolysis of lignocellulosic biomass[J]. Chemical Society Reviews, 2014, 43: 7594-7623. doi: 10.1039/c3cs60414d pmid: 24801125
[6]	SULIMAN W, HARSH J B, ABU-LAIL N I, et al. Influence of feedstock source and pyrolysis temperature on biochar bulk and surface properties[J]. Biomass and Bioenergy, 2016, 48: 37-48.
[7]	HUANG J, LIU C, TONG H, et al. Theoretical studies on pyrolysis mechanism of xylopyranose[J]. Computational and Theoretical Chemistry, 2012, 1001: 44-50. doi: 10.1016/j.comptc.2012.10.015
[8]	ZHANG Z, LIU C, LI H, et al. Theoretical studies of pyrolysis mechanism of xylan monomer[J]. Acta Chimica Sinica, 2011, 69(18):2099-2107.
[9]	GEIM A K. Graphene: Status and prospects[J]. Science, 2009, 324: 1530-1534. doi: 10.1126/science.1158877 pmid: 19541989
[10]	IIJIMA S. Helical microtubules of graphitic carbon[J]. Nature, 1991, 354: 56-58. doi: 10.1038/354056a0
[11]	KROTO H W, HEATH J R, O'BRIEN S C, et al. C60: Buckminsterfullerene[J]. Nature, 1985, 318: 162-163. doi: 10.1038/318162a0
[12]	DUBEY R, GURUVIAH V. Review of carbon-based electrode materials for supercapacitor energy storage[J]. Ionics, 2019, 25(4): 1419-1445. doi: 10.1007/s11581-019-02874-0
[13]	PAN H, LI J, FENG Y. Carbon nanotubes for supercapacitor[J]. Nanoscale Research Letters, 2010, 5(3): 654. doi: 10.1007/s11671-009-9508-2 pmid: 20672061
[14]	PANDOLFO A G, HOLLENKAMP A F. Carbon properties and their role in supercapacitors[J]. Journal of Power Sources, 2006, 157(1): 11-27. doi: 10.1016/j.jpowsour.2006.02.065
[15]	TIAN J, SHI Y, FAN W, et al. Ditungsten carbide nanoparticles embedded in electrospun carbon nanofiber membranes as flexible and high-performance supercapacitor electrodes[J]. Composites Communications, 2019, 12: 21-25. doi: 10.1016/j.coco.2018.12.003
[16]	CHEN C, WANG Y, MENG T, et al. Electrically conductive polyacrylamide/carbon nanotube hydrogel: Reinforcing effect from cellulose nanofibers[J]. Cellulose, 2019, 26(16): 8843-8851. doi: 10.1007/s10570-019-02710-8
[17]	ONISHCHENKO D V, REVA V P. Sorption properties of multilayer carbon nanotubes produced from cotton[J]. Coke and Chemistry, 2013, 56(7): 262-265. doi: 10.3103/S1068364X13070053
[18]	BI Z, KONG Q, CAO Y, et al. Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes:A review[J]. Journal of Materials Chemistry A, 2019, 7(27): 16028-16045. doi: 10.1039/C9TA04436A
[19]	CHEN J, FANG K, CHEN Q, et al. Integrated paper electrodes derived from cotton stalks for high-performance flexible supercapacitors[J]. Nano Energy, 2018, 53: 337-344. doi: 10.1016/j.nanoen.2018.08.056
[20]	CHEN Y, LU K, SONG Y, et al. A skin-inspired stretchable, self-healing and electro-conductive hydrogel with a synergistic triple network for wearable strain sensors applied in human-motion detection[J]. Nanomaterials, 2019, 9(12):1737. doi: 10.3390/nano9121737
[21]	HAN J, DING Q, MEI C, et al. An intrinsically self-healing and biocompatible electroconductive hydrogel based on nanostructured nanocellulose-polyaniline complexes embedded in a viscoelastic polymer network towards flexible conductors and electrodes[J]. Electrochimica Acta, 2019, 318: 660-672. doi: 10.1016/j.electacta.2019.06.132
[22]	CAI J, NIU H, WANG H, et al. High-performance supercapacitor electrode from cellulose-derived, inter-bonded carbon nanofibers[J]. Journal of Power Sources, 2016, 324: 302-308. doi: 10.1016/j.jpowsour.2016.05.070
[23]	LI Q, DENG L, KIM J K, et al. Growth of carbon nanotubes on electrospun cellulose fibers for high performance supercapacitors[J]. Journal of the Electrochemical Society, 2017, 164(13): A3220. doi: 10.1149/2.1181713jes
[24]	MA C, CHEN J, FAN Q, et al. Preparation and one-step activation of nanoporous ultrafine carbon fibers derived from polyacrylonitrile/cellulose blend for used as supercapacitor electrode[J]. Journal of Materials Science, 2018, 53(6): 4527-4539. doi: 10.1007/s10853-017-1887-7
[25]	FAN Q, MA C, WU L, et al. Preparation of cellulose acetate derived carbon nanofibers by ZnCl₂ activation as a supercapacitor electrode[J]. RSC Advances, 2019, 9(12): 6419-6428. doi: 10.1039/C8RA07587E
[26]	GAMINIAN H, MONTAZER M, BAHI A, et al. Capacitance performance boost of cellulose-derived carbon nanofibers via carbon and silver nanoparticles[J]. Cellulose, 2019, 26(4): 2499-2512. doi: 10.1007/s10570-018-2219-z
[27]	SONG Y, ZHANG W, HE S, et al. Perylene diimide and luminol as potential-resolved electrochemiluminescence nanoprobes for dual targets immunoassay at low potential[J]. ACS Applied Materials & Interfaces, 2019, 11(37): 33676-33683.
[28]	HAN J, WANG S, ZHU S, et al. Electrospun core-shell nanofibrous membranes with nanocellulose-stabilized carbon nanotubes for use as high-performance flexible supercapacitor electrodes with enhanced water resistance, thermal stability, and mechanical toughness[J]. ACS Applied Materials & Interfaces, 2019, 11(47):44624-44635.
[29]	LI Q, XIE S, SEREM W K, et al. Quality carbon fibers from fractionated lignin[J]. Green Chemistry, 2017, 19(7): 1628-1634. doi: 10.1039/C6GC03555H
[30]	YOUE W J, LEE S M, LEE S S, et al. Characterization of carbon nanofiber mats produced from electrospun lignin-g-polyacrylonitrile copolymer[J]. International Journal of Biological Macromolecules, 2016, 82: 497-504. doi: 10.1016/j.ijbiomac.2015.10.022
[31]	LIN J, ZHAO G. Preparation and characterization of high surface area activated carbon fibers from lignin[J]. Polymers, 2016, 8(10):369. doi: 10.3390/polym8100369
[32]	GEIM A K, NOVOSELOV K S. The rise of graphene[J]. Nature Materials, 2007, 6(3): 183-191. doi: 10.1038/nmat1849 pmid: 17330084
[33]	HUANG Y, LIANG J, CHEN Y. An overview of the applications of graphene-based materials in supercapacitors[J]. Small, 2012, 8(12): 1805-1834. doi: 10.1002/smll.201102635 pmid: 22514114
[34]	HUANG Z, LI L, WANG Y, et al. Polyaniline/graphene nanocomposites towards high-performance supercapacitors:A review[J]. Composites Communications, 2018, 8: 83-91. doi: 10.1016/j.coco.2017.11.005
[35]	PURKAIT T, SINGH G, SINGH M, et al. Large area few-layer graphene with scalable preparation from waste biomass for high-performance supercapacitor[J]. Scientific Reports, 2017, 7(1): 15239. doi: 10.1038/s41598-017-15463-w pmid: 29127348
[36]	GAO K, NIU Q, TANG Q, et al. Graphene-like 2D porous carbon nanosheets derived from cornstalk pith for energy storage materials[J]. Journal of Electronic Materials, 2018, 47(1): 337-346. doi: 10.1007/s11664-017-5771-7
[37]	LUAN Y, WANG L, GUO S, et al. A hierarchical porous carbon material from a loofah sponge network for high performance supercapacitors[J]. RSC Advances, 2015, 5(53): 42430-42437. doi: 10.1039/C5RA05688H
[38]	WU M, LI P, LI Y, et al. Enteromorpha based porous carbons activated by zinc chloride for supercapacitors with high capacity retention[J]. RSC Advances, 2015, 5(21): 16575-16581. doi: 10.1039/C4RA13428A
[39]	WU M B, LI L Y, LIU J, et al. Template-free preparation of mesoporous carbon from rice husks for use in supercapacitors[J]. New Carbon Materials, 2015, 30(5): 471-475. doi: 10.1016/S1872-5805(15)60201-3
[40]	KARTHIKEYAN K, AMARESH S, LEE S N, et al. Construction of high-energy-density supercapacitors from pine-cone-derived high-surface-area carbons[J]. ChemSusChem, 2014, 7(5): 1435-1442. doi: 10.1002/cssc.201301262 pmid: 24648276
[41]	WU M B, LI R C, HE X J, et al. Microwave-assisted preparation of peanut shell-based activated carbons and their use in electrochemical capacitors[J]. New Carbon Materials, 2015, 30(1): 86-89. doi: 10.1016/S1872-5805(15)60178-0
[42]	KOUCHACHVILI L, MAFFEI N, ENTCHEV E. Infested ash trees as a carbon source for supercapacitor electrodes[J]. Journal of Porous Materials, 2015, 22(4): 979-988. doi: 10.1007/s10934-015-9972-2
[43]	WANG D, GENG Z, LI B, et al. High performance electrode materials for electric double-layer capacitors based on biomass-derived activated carbons[J]. Electrochimica Acta, 2015, 173: 377-384. doi: 10.1016/j.electacta.2015.05.080
[44]	WANG K, ZHAO N, LEI S, et al. Promising biomass-based activated carbons derived from willow catkins for high performance supercapacitors[J]. Electrochimica Acta, 2015, 166: 1-11. doi: 10.1016/j.electacta.2015.03.048
[45]	REDONDO E, CARRETERO-GONZÁLEZ J, GOIKOLEA E, et al. Effect of pore texture on performance of activated carbon supercapacitor electrodes derived from olive pits[J]. Electrochimica Acta, 2015, 160: 178-184. doi: 10.1016/j.electacta.2015.02.006
[46]	TAN X F, LIU S B, LIU Y G, et al. Biochar as potential sustainable precursors for activated carbon production: Multiple applications in environmental protection and energy storage[J]. Bioresource Technology, 2017, 227: 359-372. doi: 10.1016/j.biortech.2016.12.083
[47]	ZHANG G, CHEN Y, CHEN Y, et al. Activated biomass carbon made from bamboo as electrode material for supercapacitors[J]. Materials Research Bulletin, 2018, 102: 391-398. doi: 10.1016/j.materresbull.2018.03.006
[48]	TIAN N, GAO M, LIU X H, et al. Activated carbon derived from walnut green peel as an electrode material for high-performance supercapacitors[J]. Biomass Conversion and Biorefinery, 2022, 1:1-9. doi: 10.1007/s13399-010-0002-y
[49]	MARTIN-MARTINEZ M, BARREIRO M F F, SILVA A M T, et al. Lignin-based activated carbons as metal-free catalysts for the oxidative degradation of 4-nitrophenol in aqueous solution[J]. Applied Catalysis B: Environmental, 2017, 219: 372-378. doi: 10.1016/j.apcatb.2017.07.065
[50]	CHEN W, ZHOU X, SHI S, et al. Synergistical enhancement of the electrochemical properties of lignin-based activated carbon using NH₃·H₂O dielectric barrier discharge plasma[J]. RSC Advances, 2017, 7(12):7392-7400. doi: 10.1039/C6RA26010A
[51]	ZHANG W, YIN J, LIN Z, et al. Facile preparation of 3D hierarchical porous carbon from lignin for the anode material in lithium ion battery with high rate performance[J]. Electrochimica Acta, 2015, 176: 1136-1142. doi: 10.1016/j.electacta.2015.08.001
[52]	XU X, ZHOU J, NAGARAJU D H, et al. Flexible, highly graphitized carbon aerogels based on bacterial cellulose/lignin: Catalyst-free synthesis and its application in energy storage devices[J]. Advanced Functional Materials, 2015, 25(21): 3193-3202. doi: 10.1002/adfm.v25.21
[53]	YUE Y, WANG Y, LI J, et al. High strength and ultralight lignin-mediated fire-resistant aerogel for repeated oil/water separation[J]. Carbon, 2022, 193: 285-297. doi: 10.1016/j.carbon.2022.03.015
[54]	LI Z, BAI Z, MI H, et al. Biowaste-derived porous carbon with tuned microstructure for high-energy quasi-solid-state supercapacitors[J]. ACS Sustainable Chemistry & Engineering, 2019, 7:13127-13135.
[55]	HUANG J, WU J, DAI F, et al. 3D honeycomb-like carbon foam synthesized with biomass buckwheat flour for high-performance supercapacitor electrodes[J]. Chemical Communications, 2019, 55:9168-9171. doi: 10.1039/C9CC03039E
[56]	SU L, KONG L, HAO S, et al. Honeycomb-like porous carbon with nanographitic domains, supported on graphene layers:Applicability for lithium/sodium storage[J]. ACS Sustainable Chemistry & Engineering, 2019, 7:10986-10994.
[57]	PARK S K, KWON S H, LEE S G, et al. 10⁵ cyclable pseudocapacitive Na-ion storage of hierarchically structured phosphorus-incorporating nanoporous carbons in organic electrolytes[J]. ACS Energy Letters, 2018, 3:724-732. doi: 10.1021/acsenergylett.8b00068
[58]	CHEN C, HUANG Y, MENG Z, et al. Multi-heteroatom doped porous carbon derived from insect feces for capacitance-enhanced sodium-ion storage[J]. Journal of Energy Chemistry, 2021, 54:482-492. doi: 10.1016/j.jechem.2020.06.025
[59]	WANG J, QIN F, GUO Z, et al. Oxygen- and nitrogen-enriched honeycomb-like porous carbon from laminaria japonica with excellent supercapacitor performance in aqueous solution[J]. ACS Sustainable Chemistry & Engineering, 2019, 7:11550-11563.
[60]	XIAO X, LI X, WANG Z, et al. Robust template-activator cooperated pyrolysis enabling hierarchically porous honeycombed defective carbon as highly-efficient metal-free bifunctional electrocatalyst for Zn-air batteries[J]. Applied Catalysis B: Environmental, 2020, 265:118603. doi: 10.1016/j.apcatb.2020.118603
[61]	ZHANG L, ZHU Y, ZHAO G, et al. O and P co-doped honeycomb-like hierarchical porous carbon derived from Sophora japonica for high performance supercapacitors[J]. RSC Advances, 2019, 9:37171-37178. doi: 10.1039/C9RA06934H
[62]	HU L, ZHU Q, WU Q, et al. Natural biomass-derived hierarchical porous carbon synthesized by an in situ hard template coupled with NaH activation for ultrahigh rate supercapacitors[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(11): 13949-13959.
[63]	SUN L, ZHOU Y, LI L, et al. Facile and green synthesis of 3D honeycomb-like N/S-codoped hierarchically porous carbon materials from bio-protic salt for flexible, temperature-resistant supercapacitors[J]. Applied Surface Science, 2019, 467-468: 382-390.
[64]	SUN N, LI Z, ZHANG X, et al. Hierarchical porous carbon materials derived from kelp for superior capacitive applications[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(9): 8735-8743.
[65]	LIANG H W, GUAN Q F, ZHU Z, et al. Highly conductive and stretchable conductors fabricated from bacterial cellulose[J]. NPG Asia Materials, 2012, 4(6): e19. doi: 10.1038/am.2012.34
[66]	WANG Z, SMITH AT, WANG W, et al. Versatile nanostructures from rice husk biomass for energy applications[J]. Angewandte Chemie, 2018, 57(42): 13722-13734.
[67]	NIU J, SHAO R, LIU M, et al. Porous carbons derived from collagen-enriched biomass: Tailored design, synthesis, and application in electrochemical energy storage and conversion[J]. Advanced Functional Materials, 2019, 29(46): 1905095. doi: 10.1002/adfm.v29.46
[68]	BI Z, KONG Q, CAO Y, et al. Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes:A review[J]. Journal of Materials Chemistry A, 2019, 27: 16028-16045.
[69]	ZHANG Y, TANG A, YANG H, et al. Applications and interfaces of halloysite nanocomposites[J]. Applied Clay Science, 2016, 119:8-17. doi: 10.1016/j.clay.2015.06.034
[70]	HE C, ZHAO J, YANG Y, et al. multiscale characteristics dynamics of hydrochar from hydrothermal conversion of sewage sludge under sub- and near-critical water[J]. Bioresource Technology, 2016, 211: 486-493. doi: 10.1016/j.biortech.2016.03.110 pmid: 27035482
[71]	YURTSEVER A, SAHINKAYA E, AKTAŞ Ö, et al. Performances of anaerobic and aerobic membrane bioreactors for the treatment of synthetic textile wastewater[J]. Bioresource Technology, 2015, 192: 564-573. doi: 10.1016/j.biortech.2015.06.024 pmid: 26093251
[72]	LI F, WANG X, SUN R. A metal-free and flexible supercapacitor based on redox-active lignosulfonate functionalized graphene hydrogels[J]. Journal of Materials Chemistry A, 2017, 5(39): 20643-20650. doi: 10.1039/C7TA03789A
[73]	YAN D, YU C, ZHANG X, et al. Nitrogen-doped carbon microspheres derived from oatmeal as high capacity and superior long life anode material for sodium ion battery[J]. Electrochimica Acta, 2016, 191: 3853-3891.
[74]	KUROSAKI F, KOYANAKA H, TSUJIMOTO M, et al. Shape-controlled multi-porous carbon with hierarchical micro-meso-macro pores synthesized by flash heating of wood biomass[J]. Carbon, 2008, 46(6): 850-857. doi: 10.1016/j.carbon.2008.02.014
[75]	WANG Y, LIN X, LIU T, et al. Wood-derived hierarchically porous electrodes for high-performance all-solid-state supercapacitors[J]. Advanced Functional Materials, 2018, 28(52): 1806207. doi: 10.1002/adfm.v28.52
[76]	BISWAL M, BANERJEE A, DEO M, et al. From dead leaves to high energy density supercapacitors[J]. Energy & Environmental Science, 2013, 6(4): 1249-1259.
[77]	ZHOU Y, REN J, YANG Y, et al. Biomass-derived nitrogen and oxygen co-doped hierarchical porous carbon for high performance symmetric supercapacitor[J]. Journal of Solid State Chemistry, 2018, 268: 149-158. doi: 10.1016/j.jssc.2018.08.041
[78]	CHEMYSHEVA D V, CHUS Y A, KLUSHIN V A, et al. Sustainable utilization of biomass refinery wastes for accessing activated carbons and supercapacitor electrode materials[J]. ChemSusChem, 2018, 11 (20): 3599-3608. doi: 10.1002/cssc.201801757 pmid: 30168655
[79]	WANG J, NIE P, DING B, et al. Biomass derived carbon for energy storage devices[J]. Journal of Materials Chemistry A, 2017, 5(6): 2411-2428. doi: 10.1039/C6TA08742F
[80]	WANG C, WU D, WANG H, et al. Biomass derived nitrogen-doped hierarchical porous carbon sheets for supercapacitors with high performance[J]. Journal of Colloid and Interface Science, 2018, 523:133-143. doi: S0021-9797(18)30251-0 pmid: 29614422
[81]	DU W, ZHANG Z, DU L, et al. Designing synthesis of porous biomass carbon from wheat straw and the functionalizing application in flexible, all-solid-state supercapacitors[J]. Journal of Alloys and Compounds, 2019, 797: 1031-1040. doi: 10.1016/j.jallcom.2019.05.207
[82]	HUANG C, SUN T, HULICOVA-JURCAKOVA D. Wide electrochemical window of supercapacitors from coffee bean-derived phosphorus-rich carbons[J]. ChemSusChem, 2013, 6(12): 2330-2339. doi: 10.1002/cssc.201300457 pmid: 24039010
[83]	CHUNG D Y, SON Y J, YOO J M, et al. Coffee waste-derived hierarchical porous carbon as a highly active and durable electrocatalyst for electrochemical energy applications[J]. ACS Applied Materials & Interfaces, 2017, 9(47): 41303-41313.
[84]	WANG J, KASKEL S. KOH activation of carbon-based materials for energy storage[J]. Journal of Materials Chemistry, 2012, 22(45): 23710-23725. doi: 10.1039/c2jm34066f
[85]	ZHANG L, ZHANG F, YANG X, et al. High-performance supercapacitor electrode materials prepared from various pollens[J]. Small, 2013, 9(8): 1342-1347. doi: 10.1002/smll.201202943 pmid: 23494916
[86]	ZHAO G, CHEN C, YU D, et al. One-step production of O-N-S co-doped three-dimensional hierarchical porous carbons for high-performance supercapacitors[J]. Nano Energy, 2018, 47: 547-555. doi: 10.1016/j.nanoen.2018.03.016
[87]	LIU X, MA C, LI J, et al. Biomass-derived robust three-dimensional porous carbon for high volumetric performance supercapacitors[J]. Journal of Power Sources, 2019, 412: 1-9. doi: 10.1016/j.jpowsour.2018.11.032
[88]	HONG K L, QIE L, ZENG R, YI Z, et al. Biomass derived hard carbon used as a high performance anode material for sodium ion batteries[J]. Journal of Materials Chemistry A, 2014, 2(32): 12733-12738. doi: 10.1039/C4TA02068E
[89]	SEVILLA M, FUERTES A B. A green approach to high-performance supercapacitor electrodes: The chemical activation of hydrochar with potassium bicarbonate[J]. ChemSusChem, 2016, 9: 1880-1888. doi: 10.1002/cssc.201600426 pmid: 27273466
[90]	GHOSH S, SANTHOSH R, JENIFFER S, et al. Natural biomass derived hard carbon and activated carbons as electrochemical supercapacitor electrodes[J]. Scientific Reports, 2019, 9(1): 16315. doi: 10.1038/s41598-019-52006-x pmid: 31704953
[91]	WANG Y, QU Q, GAO S, et al. Biomass derived carbon as binder-free electrode materials for supercapacitors[J]. Carbon, 2019, 155: 706-726. doi: 10.1016/j.carbon.2019.09.018
[92]	SUN L, FU Y, TIAN C, et al. Isolated boron and nitrogen sites on porous graphitic carbon synthesized from nitrogen-containing chitosan for supercapacitors[J]. ChemSusChem, 2014, 7(6): 1637-1646. doi: 10.1002/cssc.201400048 pmid: 24692324
[93]	LUO W, WANG B, HERON C G, et al. Pyrolysis of cellulose under ammonia leads to nitrogen-doped nanoporous carbon generated through methane formation[J]. Nano Letters, 2014, 14(4): 2225-2229. doi: 10.1021/nl500859p pmid: 24679142
[94]	LI H, YUAN D, TANG C, et al. Lignin-derived interconnected hierarchical porous carbon monolith with large areal/volumetric capacitances for supercapacitor[J]. Carbon, 2016, 100: 151-157. doi: 10.1016/j.carbon.2015.12.075
[95]	XIA C, SHI S Q. Self-activation for activated carbon from biomass:Theory and parameters[J]. Green Chemistry, 2016, 18(7): 2063-2071. doi: 10.1039/C5GC02152A
[96]	SAHA D, LI Y, BI Z, et al. Studies on supercapacitor electrode material from activated lignin-derived mesoporous carbon[J]. Langmuir, 2014, 30(3): 900-910. doi: 10.1021/la404112m pmid: 24400670
[97]	PENG H, YAO B, WEI X, et al. Pore and heteroatom engineered carbon foams for supercapacitors[J]. Advanced Energy Materials, 2019, 9(19):1803665. doi: 10.1002/aenm.v9.19
[98]	TIAN J, LIU Z, LI Z, et al. Hierarchical S-doped porous carbon derived from by-product lignin for high-performance supercapacitors[J]. RSC Advances, 2017, 7(20): 12089-12097. doi: 10.1039/C7RA00767A
[99]	HU S, ZHANG S, PAN N, et al. High energy density supercapacitors from lignin derived submicron activated carbon fibers in aqueous electrolytes[J]. Journal of Power Sources, 2014, 270: 106-112. doi: 10.1016/j.jpowsour.2014.07.063
[100]	CHEN L F, HUANG Z H, LIANG H W, et al. Flexible all-solid-state high-power supercapetitor fabricated with nitrogen-doped carbon nanofiber electrode material derived from bacterial cellulose[J]. Energy & Environmental Science, 2013, 6(11): 3331-3338.
[101]	WANG H, WANG C, DANG B, et al. Nitrogen, sulfur, phosphorous co-doped interconnected porous carbon nanosheets with high defect density for enhancing supercapacitor and lithium-ion battery properties[J]. ChemElectroChem, 2018, 5(17): 2367-2375. doi: 10.1002/celc.v5.17
[102]	CHEN X, CHI M, XING L, et al. Natural plant template derived cellular framework porous carbon as a high-rate and long-life electrode material for energy storage[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(6): 5845-5855.
[103]	LIU S, LIANG Y, ZHOU W, et al. Large-scale synthesis of porous carbon via one-step CuCl₂ activation of rape pollen for high-performance supercapacitors[J]. Journal of Materials Chemistry A, 2018, 6(25): 12046-12055. doi: 10.1039/C8TA02838A
[104]	LI Y, WANG G, WEI T, et al. Nitrogen and sulfur co-doped porous carbon nanosheets derived from willow catkin for supercapacitors[J]. Nano Energy, 2016, 19: 165-175. doi: 10.1016/j.nanoen.2015.10.038
[105]	HU Y, TONG X, ZHUO H, et al. Biomass-based porous N-self-doped carbon framework/polyaniline composite with outstanding supercapacitance[J]. AC Sustainable Chemistry & Engineering, 2017, 5(10): 8663-8674.
[106]	YANG M, KIM D S, HONG S B, et al. MnO₂ nanowire/biomass-derived carbon from hemp stem for high-performance supercapacitors[J]. Langmuir, 2017, 33(21): 5140-5147. doi: 10.1021/acs.langmuir.7b00589
[107]	HE S, CHEN W. Application of biomass-derived flexible carbon cloth coated with MnO₂ nanosheets in supercapacitors[J]. Journal of Power Sources, 2015, 294: 150-158. doi: 10.1016/j.jpowsour.2015.06.051

原料	比表面积/(m²·g^-1)	应用	参考文献
豆渣	1 276.0	超级电容器：281.4 F/g (0.5 A/g)	[54]
荞麦粉	154.0	超级电容器：767.0 F/g (1.0 A/g)	[55]
脱脂棉	1 523.0	钠离子储能设备：1 390.1 mA·h/g (0.2 A/g)	[56]
木质纤维素	1 299.0	钠离子储能设备：233.8 F/g	[57]
蚕砂	496.0	钠离子电池：331.7 mA·h/g (20.0 mA/g)	[58]
海带	1 986.0	超级电容器：381.0 F/g (1.0 A/g)	[59]
明胶	3 099.0	锌空气电池：154.2 mA/cm (1.0 V)	[60]
苦参	2 068.9	超级电容器：386.0 F/g (1.0 A/g)	[61]