Research progress on preparation methods of medium and low temperature SOFC electrolytes

doi:10.3969/j.issn.2097-0706.2022.08.005

Abstract

Abstract:

Solid oxide fuel cells （SOFCs） can convert chemical energy into electric energy through the electrochemical reaction between hydrogen and oxygen, which is in line with the clean and low carbon orientation and is conducive to the realization of dual carbon target. Reducing the thickness of the electrolytes is beneficial for lowering the operating temperature of conventional SOFCs and improving their electrochemical performances in medium and low temperatures （< 600 ℃）. The main process characteristics and research progress of several typical electrolyte preparation techniques are reviewed, and their advantages and limitations of electrolytes' industrial production are analysed.It is pointed out that physical vapor deposition represented by pulsed laser deposition and magnetron sputtering is more in line with the concept of clean production and more suitable for industrial production.

Key words: carbon neutrality, clean and low carbon, solid oxide fuel cell, electrolyte, thin film, medium and low temperature, physical vapor deposition, perovskite

CLC Number:

TK019:TM911.4

YANG Ying, ZHANG Yanxiang, YAN Mufu. Research progress on preparation methods of medium and low temperature SOFC electrolytes[J]. Integrated Intelligent Energy, 2022, 44(8): 50-57.

Figures/Tables 13

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References 53

[1]	冯刚. 《中国气候变化蓝皮书(2021)》发布[J]. 环境, 2021(11):75-77.
[2]	中华人民共和国国务院. 《新时代的中国能源发展》白皮书[EB/OL].(2020-12-21) [2022-05-26] http://www.scio.gov.cn/zfbps/ndhf/42312/Document/1695299/1695299.htm.
[3]	WACHSMAN E D, KANG T L. Lowering the temperature of solid oxide fuel cells[J]. Science, 2011, 334:935-939. doi: 10.1126/science.1204090
[4]	HONG S, LEE D, LIM Y, et al. Yttria-stabilized zirconia thin films with restrained columnar grains for oxygen ion conducting electrolytes[J]. Ceramics International, 2016, 42(15):16703-16709. doi: 10.1016/j.ceramint.2016.07.123
[5]	LIM Y, HONG S, BAE J, et al. Influence of deposition temperature on the microstructure of thin-film electrolyte for SOFCs with a nanoporous AAO support structure[J]. International Journal of Hydrogen Energy, 2017, 42(15):10199-10207. doi: 10.1016/j.ijhydene.2017.03.148
[6]	IONOV I V, SOLOVYEV A A, SHIPILOVA A V, et al. Reactive co-sputter deposition of nanostructured cermet anodes for solid oxide fuel cells[J]. Japanese Journal of Applied Physics, 2018, 57(1S):01AF07. doi: 10.7567/JJAP.57.01AF07
[7]	WANG H, JI W, ZHANG L, et al. Preparation of YSZ films by magnetron sputtering for anode-supported SOFC[J]. Solid State Ionics, 2011, 192(1):413-418. doi: 10.1016/j.ssi.2010.05.022
[8]	KUZMIN A V, STROEVA A Y, PLEKHANOV M S, et al. Chemical solution deposition and characterization of the La_1-_хSr_xScO_3-_α thin films on La_1-_xSr_xMnO_3-_α substrate[J]. International Journal of Hydrogen Energy, 2018, 43(41):19206-19212. doi: 10.1016/j.ijhydene.2018.08.114
[9]	HAILE S M. Fuel cell materials and components[J]. Acta Materialia, 2003, 51(19):5981-6000. doi: 10.1016/j.actamat.2003.08.004
[10]	PEDERSON L R, SINGH P, ZHOU X D. Application of vacuum deposition methods to solid oxide fuel cells[J]. Vacuum, 2006, 80(10):1066-1083. doi: 10.1016/j.vacuum.2006.01.072
[11]	REZUGINA E, THOMANN A L, HIDALGO H, et al. Ni-YSZ films deposited by reactive magnetron sputtering for SOFC applications[J]. Surface and Coatings Technology, 2010, 204(15):2376-2380. doi: 10.1016/j.surfcoat.2010.01.006
[12]	TULLER H L. Ionic conduction in nanocrystalline materials[J]. Solid State Ionics, 2000, 131(1-2):143-157. doi: 10.1016/S0167-2738(00)00629-9
[13]	HUANG H, NAKAMURA M, SU P, et al. High-performance ultrathin solid oxide fuel cells for low-temperature operation[J]. Journal of the Electrochemical Society, 2007, 154(1):B20-B24. doi: 10.1149/1.2372592
[14]	PARK T, CHO G Y, LEE Y H, et al. Effect of anode morphology on the performance of thin film solid oxide fuel cell with PEALD YSZ electrolyte[J]. International Journal of Hydrogen Energy, 2016, 41(22):9638-9643. doi: 10.1016/j.ijhydene.2016.04.092
[15]	ISHIHARA T, MATSUDA H, TAKITA Y. Doped LaGaO₃ perovskite type oxide as a new oxide ionic conductor[J]. Journal of the American Chemical Society, 1994, 116(9):3801-3803. doi: 10.1021/ja00088a016
[16]	HUANG K, WAN J H, GOODENOUGH J B. Increasing power density of LSGM-based solid oxide fuel cells using new anode materials[J]. Journal of the Electrochemical Society, 2001, 148(7): A788-A794. doi: 10.1149/1.1378289
[17]	ISHIHARA T, TABUCHI J, ISHIKAWA S, et al. Recent progress in LaGaO₃ based solid electrolyte for intermediate temperature SOFCs[J]. Solid State Ionics, 2006, 177(19-25):1949-1953. doi: 10.1016/j.ssi.2006.01.044
[18]	MOLINA-REYES J, TIZNADO H, SOTO G, et al. Physical and electrical characterization of yttrium-stabilized zirconia(YSZ) thin films deposited by sputtering and atomic-layer deposition[J]. Journal of Materials Science, 2018, 29(18):15349-15357.
[19]	SOLOVYEV A A, RABOTKIN S V, KUTERBEKOV K A, et al. Comparison of sputter-deposited single and multilayer electrolytes based on gadolinia-doped ceria and yttria-stabilized zirconia for solid oxide fuel cells[J]. International Journal of Electrochemical Science, 2020, 15:231-240.
[20]	KHARTON V V, MARQUES F, ATKINSON A. Transport properties of solid oxide electrolyte ceramics:A brief review[J]. Solid State Ionics, 2004, 174(1-4):135-149. doi: 10.1016/j.ssi.2004.06.015
[21]	ZHANG Y, HUANG X, ZHE L, et al. A study of the process parameters for yttria-stabilized zirconia electrolyte films prepared by screen-printing[J]. Journal of Power Sources, 2006, 160(2):1065-1073. doi: 10.1016/j.jpowsour.2006.02.074
[22]	BAHARUDDIN N A, ABDUL RAHMAN N F, RAHMAN HABD, et al. Fabrication of high-quality electrode films for solid oxide fuel cell by screen printing: A review on important processing parameters[J]. International Journal of Energy Research, 2020, 44(11): 8296-8313. doi: 10.1002/er.5518
[23]	XU X, XIA C, HUANG S, et al. YSZ thin films deposited by spin-coating for IT-SOFCs[J]. Ceramics International, 2005, 31(8):1061-1064. doi: 10.1016/j.ceramint.2004.11.005
[24]	CHEN K, ZHE L, NA A, et al. Fabrication and performance of anode-supported YSZ films by slurry spin coating[J]. Solid State Ionics, 2007, 177(39-40):3455-3460. doi: 10.1016/j.ssi.2006.10.003
[25]	HUI R, WANG Z, YICK S, et al. Fabrication of ceramic films for solid oxide fuel cells via slurry spin coating technique[J]. Journal of Power Sources, 2007, 172(2):840-844. doi: 10.1016/j.jpowsour.2007.05.036
[26]	KIM H J, KIM M, NEOH K C, et al. Slurry spin coating of thin film yttria stabilized zirconia/gadolinia doped ceria bi-layer electrolytes for solid oxide fuel cells[J]. Journal of Power Sources, 2016, 327:401-407. doi: 10.1016/j.jpowsour.2016.07.080
[27]	MENG G, SONG H, XIA C, et al. Novel CVD techniques for Micro- and IT-SOFC fabrication[J]. Fuel Cells, 2004, 4(1-2):48-55. doi: 10.1002/fuce.200400006
[28]	CHOY K L. Chemical vapour deposition of coatings[J]. Progress in Materials Science, 2003, 48(2):57-170. doi: 10.1016/S0079-6425(01)00009-3
[29]	EHSAN M A, SOHAIL M, JAMIL R, et al. Single-step fabrication of nanostructured palladium thin films via aerosol-assisted chemical vapor deposition(AACVD) for the electrochemical detection of hydrazine[J]. Electrocatalysis, 2019, 10(3):214-221. doi: 10.1007/s12678-019-00513-w
[30]	MIRMOGHTADAEI G, GHOSALYA M K, ARTIGLIA L, et al. Strong promoting effect of gold nanoparticles on the CO abatement catalytic activity of CoO_x/Clay-bonded SiC catalysts produced by AA-MOCVD method using Co(acac)₂ as precursor[J]. ChemistrySelect, 2020, 5(44):13878-13887. doi: 10.1002/slct.202003728
[31]	MENG G, SONG H, QIANG D, et al. Application of novel aerosol-assisted chemical vapor deposition techniques for SOFC thin films[J]. Solid State Ionics, 2004, 175(1-4):29-34. doi: 10.1016/j.ssi.2004.09.038
[32]	JANG D Y, KIM M, KIM J W, et al. High performance anode-supported solid oxide fuel cells with thin film yttria-stabilized zirconia membrane prepared by aerosol-assisted chemical vapor deposition[J]. Journal of The Electrochemical Society, 2017, 164(6):F484-F490. doi: 10.1149/2.0181706jes
[33]	JANG D Y, KIM H K, KIM J W, et al. Low-temperature performance of yttria-stabilized zirconia prepared by atomic layer deposition[J]. Journal of Power Sources, 2015, 274:611-618. doi: 10.1016/j.jpowsour.2014.10.022
[34]	SHIN J W, GO D, KYE S H, et al. Review on process-microstructure-performance relationship in ALD-engineered SOFCs[J]. Journal of Physics Energy, 2019, 1(4):042002. doi: 10.1088/2515-7655/ab30a0
[35]	HONG S, BAE J, KOO B, et al. High-performance ultra-thin film solid oxide fuel cell using anodized-aluminum-oxide supporting structure[J]. Electrochemistry Communications, 2014, 47:1-4. doi: 10.1016/j.elecom.2014.07.008
[36]	CHA S W, GU Y C, LEE Y, et al. Effects of carbon contaminations on Y₂O₃-stabilized ZrO₂ thin film electrolyte prepared by atomic layer deposition for thin film solid oxide fuel cells[J]. CIRP Annals, 2016, 65(1):515-518. doi: 10.1016/j.cirp.2016.04.079
[37]	PARK T, CHO G Y, LEE Y H, et al. Effect of anode morphology on the performance of thin film solid oxide fuel cell with PEALD YSZ electrolyte[J]. International Journal of Hydrogen Energy, 2016, 41(22):9638-9643. doi: 10.1016/j.ijhydene.2016.04.092
[38]	KUPPUSAMI P, RAGHUNATHAN V S. Status of pulsed laser deposition: Challenges and opportunities[J]. Surface Engineering, 2006, 22(2):81-83. doi: 10.1179/174329406X98502
[39]	HOBEIN B, TIETZ F, STÖVER D, et al. Pulsed laser deposition of yttria stabilized zirconia for solid oxide fuel cell applications[J]. Journal of Power Sources, 2002, 105(2):239-242. doi: 10.1016/S0378-7753(01)00945-4
[40]	JOO J H, CHOI G M. Open-circuit voltage of ceria-based thin film SOFC supported on nano-porous alumina[J]. Solid State Ionics, 2007, 178(29-30):1602-1607. doi: 10.1016/j.ssi.2007.10.006
[41]	SON J W, MYUNG D H, HWANG J, et al. Potential and limitation of application of pulsed laser deposited nano-structure LSC thin film cathode to YSZ electrolyte SOFC[J]. ECS Transactions, 2011, 35(1):2423-2427. doi: 10.1149/1.3570239
[42]	BOYDENS F, MAHIEU S, HAEMERS J, et al. Influence of the magnetic field configuration on the reactive sputter deposition of TiN[J]. Physica Status Solidi (A):Applications and Materials Science, 2010, 207(1):124-128.
[43]	INFORTUNA A, HARVEY A S, GAUCKLER L J. Microstructures of CGO and YSZ thin films by pulsed laser deposition[J]. Advanced Functional Materials, 2008, 18(1):127-135. doi: 10.1002/adfm.200700136
[44]	KWON C, SON J, LEE J, et al. High-performance micro-solid oxide fuel cells fabricated on nanoporous anodic aluminum oxide templates[J]. Advanced Functional Materials, 2011, 21(6):1154-1159. doi: 10.1002/adfm.201002137
[45]	NOH H S, LEE H, LEE J H, et al. Thin film electrolyte micro-SOFC: Fabrication and performance improvement through thin film electrolyte and nano-structure electrodes[J]. ECS Transactions, 2009, 25(2):873-879. doi: 10.1149/1.3205607
[46]	CHO S, KIM Y N, KIM J H, et al. High power density thin film SOFCs with YSZ/GDC bilayer electrolyte[J]. Electrochimica Acta, 2011, 56(16):5472-5477. doi: 10.1016/j.electacta.2011.03.039
[47]	JI S, AN J, JANG D Y, et al. On the reduced electrical conductivity of radio-frequency sputtered doped ceria thin film by elevating the substrate temperature[J]. Current Applied Physics, 2016, 16(3):324-328. doi: 10.1016/j.cap.2015.12.011
[48]	FRISON R, HEIROTH S, RUPP J L M, et al. Crystallization of 8 mol% yttria-stabilized zirconia thin-films deposited by RF-sputtering[J]. Solid State Ionics, 2013, 232:29-36. doi: 10.1016/j.ssi.2012.11.014
[49]	KANG S, LEE J, CHO G Y, et al. Scalable fabrication process of thin-film solid oxide fuel cells with an anode functional layer design and a sputtered electrolyte[J]. International Journal of Hydrogen Energy, 2020, 45(58):33980-33992. doi: 10.1016/j.ijhydene.2020.09.033
[50]	SHIN S S, KIM J H, BAE K T, et al. Multiscale structured low-temperature solid oxide fuel cells with 13 W power at 500 ℃[J]. Energy & Environmental Science, 2020, 13(10):3459-3468.
[51]	SUKESHINI M A, CUMMINS R, REITZ T L, et al. Ink-jet printing: A versatile method for multilayer solid oxide fuel cells fabrication[J]. Journal of the American Ceramic Society, 2009, 92(12):2913-2919. doi: 10.1111/j.1551-2916.2009.03349.x
[52]	HAN G D, BAE K, KANG E H, et al. Inkjet printing for manufacturing solid oxide fuel cells[J]. ACS Energy Letters, 2020, 5(5):1586-1592. doi: 10.1021/acsenergylett.0c00721
[53]	ZHU Z, GONG Z, QU P, et al. Additive manufacturing of thin electrolyte layers via inkjet printing of highly-stable ceramic inks[J]. Journal of Advanced Ceramics, 2021, 10(2):279-290. doi: 10.1007/s40145-020-0439-9